VANADIUM Basis Set Expn. C 1.351 0.043111 s 0.6008 -0.284946 0.09275 0.599744 0.03482 0.541693 16.49 0.059210 4.294 0.260308 d 1.357 0.452098 0.4861 0.374363 0.1807 0.194581 Potential n Exp. Coef. d 5 2 .377300 -.316358 2 1.235200 -2.866274 2 3.706400 -10.883734 2 13.445000 -30.683535 1 37.798800 -11.546134 s-d 6 2 .241200 .046276 2 1.313700 116.585625 2 1.551000 -206.265710 2 1.895600 116.925031 1 7.148000 17.728772 0 20.988400 2.970518 p-d 6 2 .205800 .023834 2 .944400 85.664988 2 1.102900 -168.829453 2 1.313800 101.257101 1 3.758400 6.586527 0 3.913800 5.590046 spin-orbit operator p-d 6 2 .205800 .001068 2 .944400 3.228808 2 1.102900 -6.576396 2 1.313800 3.452854 1 3.758400 -.126410 0 3.913800 .017926 d 5 2 .377300 -.002359 2 1.235200 .008189 2 3.706400 -.007325 2 13.445000 .015336 1 37.798800 .070118 Basis Set Expn. C (n=3) C (n=4) (-3.2290) (-0.2319) s 43.25 -0.009034 0.002038 13.51 0.055107 -0.011248 5.567 -0.409361 0.106531 1.452 0.645757 -0.206980 0.5744 0.590024 -0.325408 0.09282 0.002747 0.618081 0.03553 0.001181 0.534621 (-2.0265) p 40.32 -0.010349 16.46 0.004689 7.024 -0.071800 2.790 0.259188 1.146 0.596145 0.4473 0.283967 (-0.5004) d 30.22 0.022431 8.272 0.121119 2.758 0.327129 0.9421 0.472578 0.3053 0.349066 0.08200 0.063194 Potential n Exp. Coef. d 4 2 8.962500 -3.136448 2 26.809300 -23.110026 2 86.549900 -57.052871 1 287.728300 -8.138614 s-d 6 2 2.225300 -46.461235 2 2.783300 98.908827 2 3.805300 -175.341506 2 5.070000 152.276135 1 1.673200 9.725781 0 18.827600 3.107725 p-d 6 2 2.212200 -17.858910 2 2.625300 58.309347 2 3.527600 -111.785050 2 4.779400 115.283333 1 8.183900 -5.636391 0 17.387000 5.509440 spin-orbit operator p-d 6 2 2.212200 -.366042 2 2.625300 1.345598 2 3.527600 -3.108108 2 4.779400 3.820584 1 8.183900 -.800606 0 17.387000 .053530 d 4 2 8.962500 .014099 2 26.809300 .089784 2 86.549900 .375741 1 287.728300 .568594