CH271 Chemical Engineering Thermodynamics

Fall 2002

 

 

Catalog Description:

            The fundamentals of thermodynamics, including real fluids, thermodynamic properties of gases, and thermodynamics of solutions.

 

Pre-requisites:

            CM104 of CM132, MA132 and PH131

 

Co-requisites:

            CH250 and CM371

 

Instructor:     

            Professor Ruth Baltus

            226 CAMP

            x2368

            baltus@clarkson.edu

 

Office Hours:

            Mon, Tues, Wed, Thurs 1:30-3:00 PM or by appointment

 

Textbook:

            Introductory Chemical Engineering Thermodynamics

            J.R. Elliott and C.T. Lira

            Prentice Hall, 1999

 

            The authors maintain a website for this book that contains a list of text errors, additional practice problems as well as other information. You may also download Excel spreadsheets for many of the calculations we will do in this course from this website. Website address is:  http://www.egr.msu.edu/~lira/thermtxt.htm

 

Objectives:

1.      For students to learn the fundamental principles of thermodynamics. [1]

2.      For students to be able to use equations of state and thermodynamic tables to determine various thermodynamic state properties for single component systems. [1]

3.      To acquaint students with the applications of the first and second laws of thermodynamics. [1]

4.      Analyze cyclic processes and determine energy conversion efficiencies. [1]

5.      Students will be able to relate the properties of real fluids to those for ideal gases. [1]

 

Topical Outline:

1.      Thermodynamic Quantities – pressure, temperature, energy (Chapter 1)

2.      Steam Tables (Chapter 1)

3.      Work (Chapter 2)

4.      First Law of Thermodynamics – Energy Balance (Chapter 2)

5.      Heat Capacities (Chapter 2)

6.      Lost Work/Reversibility (Chapter 2)

7.      Cubic Equations of State (Chapter 6)

8.      Departure Functions (Chapter 7)

9.      Entropy (Chapter 3)

10.  Entropy Balance (Chapter 3)

11.  Carnot Cycle (Chapter 3)

12.  Process Efficiency (Chapter 3)

13.  Rankine Cycle (Chapter 4)

14.  Refrigeration Cycle (Chapter 4)

15.  Fundamental Property Relation (Chapter 5)

16.  Maxwell’s Relations (Chapter 5)

17.  Phase Equilibrium for Single Component (Chapter 8)

18.  Fugacity (Chapter 8)

 

Course Philosophy:

            It is my philosophy that students learn engineering by doing engineering. That means a lot of problem solving. We will spend a considerable amount of class time doing problems – individually, in small groups and together as a class. You should come to each class prepared to work on problems by bringing your textbook and a calculator. Active participation in these class exercises is strongly encouraged.

 

Homework:

            Homework will be assigned each week in class. A list of assignments will also be maintained on the web (http://www.clarkson.edu/~baltus/ch271f02.html). Homework solutions will also be posted on the web. It is expected that a complete set of homework solutions become part of your notebook for this course. You are encouraged to check your solution with the instructor’s and to make appropriate corrections before adding your solution to your notebook.

 

            When done appropriately, collaborative learning can help all involved. You are encouraged to work with your classmates to discuss and complete homework assignments. However, you will learn little if you do not struggle with the assignments on your own before discussing solutions with your classmates.

 

            Assignments will be collected during class time – late assignments will not be accepted. In order to facilitate collecting and dispersing assignments, you are asked to STAPLE all sheets together in the upper right corner, put your name on each sheet, fold the assignment lengthwise and put your name on the back page with last name first (so that your name shows clearly when fold is on the left side).

 

Hour Exams:

            Hour exams will be given during class time on Monday September 23, Monday October 21 and Monday November 25. Exams will be open book, open notes.

 

Grading:

            Hour Exams:            60%

                        (best score will count 30%, second best score 20%,  poorest score 10%)

            Final Exam:            30%

            Homework:            10%

 

Student Learning Outcomes (to be evaluated via homework and exams)

1.      Students will learn the concepts of internal energy, heat, work, enthalpy and entropy. [1]

2.      Students will be able to distinguish between intensive and extensive properties. [1]

3.      Students will become familiar with thermodynamic property diagrams. [2]

4.      Students will learn about various equations of state. [2]

5.      Students will be able to formulate energy balances for various processes. [3]

6.      Students will learn standard models for cyclic heat engines, refrigerators and heat pumps.

7.      Students will know how to calculate thermodynamic efficiencies and coefficients of performance for cyclic processes and for pumps and turbines. [2]

8.      Students will learn fundamental equations relating thermodynamic properties. [5]

9.      Students will become familiar with Maxwell’s Relations. [5]

 

Engineering Topics:

            Engineering Science: 3 credits

 

Date Prepared: August 22, 2002