-
Development of ultrathin electronic
and optical devices and sensors based on nanoparticulate and nanostructured
films;
-
Construction of monolayers and
Langmuir-Blodgett films from surfactant-stabilized semiconductor, ferroelectric,
magnetic, and metallic nanoparticles;
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Experimental and theoretical
investigations of surface pressure vs. surface area isotherms of particulate
layers;
-
Characterization of clay platelets
and organoclay complexes on water surfaces in a Langmuir film balance;
-
Formation and characterization
of composite semiconductor, metallic, and magnetic particulate films under
monolayers;
-
Monitoring the in situ generation
of nanoparticles between the headgroups of Langmuir-Blodgett films by absorption,
emission, and surface plasmon spectroscopies;
-
Spectroscopic examination of
the surface states of semiconductor nanoparticles localized
between the headgroups of Langmuir-Blodgett films;
-
Electron and energy
transfer in organized systems:
-
Microscopic techniques:
-
Scanning probe microscopic investigation
of nanoparticles and nanostructures (STM, AFM, MFM);
-
Development of near-field scanning
optical microscopy for nanoparticle imaging (NSOM);
-
Examination of oriented growth
of nanocrystallites under monolayers (BAM);
Research Capabilities:
-
Preparation of monodisperse
nanoparticles (metallic, bi-metallic, semiconducting, magnetic, and ferroelectric)
as stable dispersions or solids.
-
Chemical and physical modifications
of nanoparticle surfaces for desired applications.
-
Organization of monodisperse
nanoparticles (in desired composition and sizes) into two-dimensional
arrays and three-dimensional networks with controllable interparticle distances.
-
Preparation of versatile ultrathin
films (with ±1.0 nm controllable thickness) from nanoparticles,
polyelectrolytes, clay and graphite platelets by:
-
spin-coating and evaporation,
-
layer-by-layer deposition by
the Langmuir-Blodgett technique, and by
-
layer-by-layer self-assembly.
-
Characterization of nanoparticles
and nanoparticulate films by a large variety of techniques including steady
state and pico-second time resolved absorption and emission spectroscopy,
surface plasmon spectroscopy, transmission and scanning electronmicroscopy,
X-ray diffractometry and reflectivity, scanning force microscopy (scanning
tunneling-, atomic force-, chemical force-, electrochemical force-, magnetic
force-, and near field optical scanning-microscopies) and electrochemical
and electro-optical measurements.
-
Nanofabrication and nanolithography
by scanning force microscopy.
-
Measuring adhesion and friction
in nanodomains and optimizing ultrathin lubricants.
-
Investigating layered magnetic
and ferroelectric nanoparticles as potential memory storage devices.
-
Developing semiconductor based
sensors, photovoltaic-, light emitting-, and electroluminescence devices.
-
Developing composite and sandwich
nanoparticles as catalysts.
Last Revised: 09/01/98
Copyright ©1998 - Thierry Cassagneau/Frederic
Guerin. All rights reserved.
Send comments to:
fendler@polaris.clarkson.edu