Research Activities of the FENDLER's Group


    Basic Research Interests:



     
  • Self-assembly of nanostructured films:

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    • Polyelectrolyte-inorganic particle nanostructured films;
    • Li-ion batteries;
    • Rectifying Devices;
  • Nanoparticulate films by the Langmuir-Blodgett technique:
    • Development of ultrathin electronic and optical devices and sensors based on nanoparticulate and nanostructured films;
    • Construction of monolayers and Langmuir-Blodgett films from surfactant-stabilized semiconductor, ferroelectric,
              magnetic, and metallic nanoparticles;
    • Experimental and theoretical investigations of surface pressure vs. surface area isotherms of particulate layers;
    • Characterization of clay platelets and organoclay complexes on water surfaces in a Langmuir film balance;
    • Formation and characterization of composite semiconductor, metallic, and magnetic particulate films under monolayers;
    • Monitoring the in situ generation of nanoparticles between the headgroups of Langmuir-Blodgett films by absorption,
              emission, and surface plasmon spectroscopies;
    • Spectroscopic examination of the surface states of semiconductor nanoparticles localized
              between the headgroups of Langmuir-Blodgett films;
     
  • Electron and energy transfer in organized systems:

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  • Microscopic techniques:

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    • Scanning probe microscopic investigation of nanoparticles and nanostructures (STM, AFM, MFM);
    • Development of near-field scanning optical microscopy for nanoparticle imaging (NSOM);
    • Examination of oriented growth of nanocrystallites under monolayers (BAM);
       
       
    Research Capabilities:

    • Preparation of monodisperse nanoparticles (metallic, bi-metallic, semiconducting, magnetic, and ferroelectric) as stable dispersions or solids.
    • Chemical and physical modifications of nanoparticle surfaces for desired applications.
    • Organization of monodisperse nanoparticles (in desired composition and sizes) into  two-dimensional arrays and three-dimensional networks with controllable interparticle distances.
    • Preparation of versatile ultrathin films (with ±1.0 nm controllable thickness) from nanoparticles, polyelectrolytes, clay and graphite platelets by:
        • spin-coating and evaporation,
        • layer-by-layer deposition by the Langmuir-Blodgett technique, and by
        • layer-by-layer self-assembly.
    • Characterization of nanoparticles and nanoparticulate films by a large variety of techniques including steady state and pico-second time resolved absorption and emission spectroscopy, surface plasmon spectroscopy, transmission and scanning electronmicroscopy, X-ray diffractometry and reflectivity, scanning force microscopy (scanning tunneling-, atomic force-, chemical force-, electrochemical force-, magnetic force-, and near field optical scanning-microscopies) and electrochemical and electro-optical measurements.
    • Nanofabrication and nanolithography by scanning force microscopy.
    • Measuring adhesion and friction in nanodomains and optimizing ultrathin lubricants.
    • Investigating layered magnetic and ferroelectric nanoparticles as potential memory storage devices.
    • Developing semiconductor based sensors, photovoltaic-, light emitting-, and electroluminescence devices.
    • Developing composite and sandwich nanoparticles as catalysts.

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    Last Revised: 09/01/98
    Copyright ©1998 - Thierry Cassagneau/Frederic Guerin. All rights reserved.
    Send comments to: fendler@polaris.clarkson.edu